Love and Betrayal: A-List Actors Accused of Cheating with Their Co-Stars
Brad Pitt and Angelina Jolie
Here’s one of the most notorious celebrity relationships ever. Pitt has a history of dating co-stars but took it too far when he cheated on Jennifer Aniston with Jolie. Aniston filed for divorce after he worked with Jolie on Mr. And Mrs. Smith in 2005.

Elle
Chemistry sparked when they filmed together on-set and they even vacationed together. However, in 2016 Jolie filed for divorce after things turned bad between them. Their cheating scandal was a huge news story at the time because they were two of the most powerful actors on the planet (via Red Book Mag).